Transport Phenomena - Delft University of Technology

Sorted by YearSorted by First Author

Binary and Ternary Vapor-Liquid Equilibrium Data of the System Ethylbenzene+Styrene+3-Methyl-N-Butylpyridinium Tetracyanoborate at Vacuum Conditions and Liquid-Liquid Equilibrium Data of Their Binary Systems

Binary and Ternary Vapor-Liquid Equilibrium Data of the System Ethylbenzene+Styrene+3-Methyl-N-Butylpyridinium Tetracyanoborate at Vacuum Conditions and Liquid-Liquid Equilibrium Data of Their Binary Systems, Mark T. G. Jongmans, Eline Hermens, Boelo Schuur, and Andre B. de Haan. Fluid Phase Equilibria 2012, 315 , 99–106.

Download

[DOI] 

Abstract

In this study, binary LLE data at 313.2, 333.2, and 353.2 K, binary VLE data in the pressure range of 3-30 kPa and ternary VLE data at 5, 10, and 15 kPa have been determined for the system ethylbenzene + styrene +[3-mebupy] [B(CN)(4)]. The IL [3-mebupy][B(CN)(4)] can increase the relative volatility of the ethylbenzene/styrene mixture from 1.4 without solvent up to 2.2 and is therefore a promising solvent. The binary and ternary VLE data were regressed separately with the NRTL model. The correlation statistics demonstrated that the NRTL model can describe the experimental data adequately. It was not possible to get a proper description of the ternary VLE data with the NRTL parameters determined solely from the binary systems. (C) 2011 Elsevier BM. All rights reserved.

BibTeX

@article{ ISI:000300476100014,
Author = {Jongmans, Mark T. G. and Hermens, Eline and Schuur, Boelo and de Haan, Andre B.},
Title = {Binary and Ternary Vapor-Liquid Equilibrium Data of the System Ethylbenzene+Styrene+3-Methyl-N-Butylpyridinium Tetracyanoborate at Vacuum Conditions and Liquid-Liquid Equilibrium Data of Their Binary Systems},
Journal = {Fluid Phase Equilibria},
Year = {2012},
Volume = {315},
Pages = {99-106},
Month = {},
Abstract = {In this study, binary LLE data at 313.2, 333.2, and 353.2 K, binary VLE data in the pressure range of 3-30 kPa and ternary VLE data at 5, 10, and 15 kPa have been determined for the system ethylbenzene + styrene +{[}3-mebupy] {[}B(CN)(4)]. The IL {[}3-mebupy]{[}B(CN)(4)] can increase the relative volatility of the ethylbenzene/styrene mixture from 1.4 without solvent up to 2.2 and is therefore a promising solvent. The binary and ternary VLE data were regressed separately with the NRTL model. The correlation statistics demonstrated that the NRTL model can describe the experimental data adequately. It was not possible to get a proper description of the ternary VLE data with the NRTL parameters determined solely from the binary systems. (C) 2011 Elsevier BM. All rights reserved.},
DOI = {10.1016/j.fluid.2011.11.027},
ISSN = {0378-3812},
Unique-ID = {ISI:000300476100014},
}

Generated by bib2html.pl (written by Patrick Riley ) on Fri Jul 28, 2017 13:53:03


Last modified: July 28 2017. © Delft University of Technology - TP group 2012